Amorphous metal

An amorphous metal (also known as metallic glass or glassy metal) is a solid lic material, usually an, with disordered atomic-scale structure. Most metals are line in their solid state, which means they have a highly ordered arrangement of s. Amorphous metals are non-crystalline, and have a. But unlike common glasses, such as window glass, which are typically electrical s, amorphous metals have good. There are several ways in which amorphous metals can be produced, including, , , , and .Previously, small batches of amorphous metals had been produced through a variety of quick-cooling methods, such as amorphous metal ribbons which had been produced by sputtering molten metal onto a spinning metal disk. The rapid cooling (in the order of millions of degrees Celsius a second) is too fast for crystals to form and the material is "locked" in a glassy state. Currently, a number of alloys with critical cooling rates low enough to allow formation of amorphous structure in thick layers (over 1 millimeter) have been produced; these are known as bulk metallic glasses (BMG). More recently, batches of amorphous steel with three times the strength of conventional steel alloys have been produced.

History
The first reported metallic glass was an (Au75Si25) produced at  by W. Klement (Jr.), Willens and  in 1960. This and other early glass-forming alloys had to be cooled extremely rapidly (on the order of one per second, 106 K/s) to avoid crystallization. An important consequence of this was that metallic glasses could only be produced in a limited number of forms (typically ribbons, foils, or wires) in which one dimension was small so that heat could be extracted quickly enough to achieve the necessary cooling rate. As a result, metallic glass specimens (with a few exceptions) were limited to thicknesses of less than one hundred.

In 1969, an alloy of 77.5%, 6% copper, and 16.5% silicon was found to have between 100 and 1000 K/s.

In 1976, H. Liebermann and C. Graham developed a new method of manufacturing thin ribbons of amorphous metal on a. This was an alloy of, , and. The material, known as , was commercialized in the early 1980s and is used for low-loss power distribution transformers. Metglas-2605 is composed of 80% iron and 20% boron, has of 373 °C and a room temperature saturation magnetization of 1.56.

In the early 1980s, glassy ingots with 5 mm diameter were produced from the alloy of 55% palladium, 22.5% lead, and 22.5% antimony, by surface etching followed with heating-cooling cycles. Using, the achievable thickness was increased to a centimeter.

Research in and  yielded multicomponent alloys based on lanthanum, magnesium, zirconium, palladium, iron, copper, and titanium, with critical cooling rate between 1 K/s to 100 K/s, comparable to oxide glasses.

In 1982, a study on amorphous metal structural relaxation indicated a relationship between the specific heat and temperature of (Fe0.5Ni0.5)83P17. As the material was heated up, the properties developed a negative relationship starting at 375 K, which was due to the change in relaxed amorphous states. When the material was annealed for periods from 1 to 48 hours, the properties developed a positive relationship starting at 475 K for all annealing periods, since the annealing induced structure disappears at that temperature. In this study, amorphous alloys demonstrated glass transition and a super cooled liquid region. Between 1988 and 1992, more studies found more glass-type alloys with glass transition and a super cooled liquid region. From those studies, bulk glass alloys were made of La, Mg, and Zr, and these alloys demonstrated plasticity even when their ribbon thickness was increased from 20 μm to 50 μm. The plasticity was a stark difference to past amorphous metals that became brittle at those thicknesses.

In 1988, alloys of lanthanum, aluminium, and copper ore were found to be highly glass-forming. Al-based metallic glasses containing  exhibited a record-type tensile mechanical strength of about 1500 MPa.

Before new techniques were found in 1990, bulk amorphous alloys of several millimeters in thickness were rare, except for a few exceptions, Pd-based amorphous alloys had been formed into rods with a 2 mm diameter by quenching, and spheres with a 10 mm diameter were formed by repetition flux melting with B2O3 and quenching.

In the 1990s new alloys were developed that form glasses at cooling rates as low as one kelvin per second. These cooling rates can be achieved by simple casting into metallic molds. These "bulk" amorphous alloys can be cast into parts of up to several centimeters in thickness (the maximum thickness depending on the alloy) while retaining an amorphous structure. The best glass-forming alloys are based on and, but alloys based on , , , , and other metals are also known. Many amorphous alloys are formed by exploiting a phenomenon called the "confusion" effect. Such alloys contain so many different elements (often four or more) that upon cooling at sufficiently fast rates, the constituent atoms simply cannot coordinate themselves into the equilibrium crystalline state before their mobility is stopped. In this way, the random disordered state of the atoms is "locked in".

In 1992, the commercial amorphous alloy, 1 (41.2% Zr, 13.8% Ti, 12.5% Cu, 10% Ni, and 22.5% Be), was developed at Caltech, as a part of  and  research of new aerospace materials.

In 2004, bulk amorphous steel was successfully produced by two groups: one at, who refers to their product as "glassy steel", and the other at the , calling theirs "DARVA-Glass 101". The product is non- at and significantly stronger than conventional steel, though a long research and development process remains before the introduction of the material into public or military use.

In 2018 a team at SLAC, the (NIST) and  reported the use of  to predict and evaluate samples of 20,000 different likely metallic glass alloys in a year. Their methods promise to speed up research and time to market for new amorphous metals alloys.

Properties
Amorphous metal is usually an rather than a pure metal. The alloys contain atoms of significantly different sizes, leading to low free volume (and therefore up to orders of magnitude higher viscosity than other metals and alloys) in molten state. The viscosity prevents the atoms moving enough to form an ordered lattice. The material structure also results in low shrinkage during cooling, and resistance to plastic deformation. The absence of, the weak spots of crystalline materials, leads to better resistance to and. Amorphous metals, while technically glasses, are also much and less brittle than oxide glasses and ceramics. Amorphous metals can be grouped in two categories, as either non-ferromagnetic, if they are composed of Ln, Mg, Zr, Ti, Pd, CA, Cu, Pt and Au, or ferromagnetic alloys, if they are composed of Fe, Co, and Ni.Thermal conductivity of amorphous materials is lower than that of crystalline metal. As formation of amorphous structure relies on fast cooling, this limits the maximum achievable thickness of amorphous structures.

To achieve formation of amorphous structure even during slower cooling, the alloy has to be made of three or more components, leading to complex crystal units with higher potential energy and lower chance of formation. The of the components has to be significantly different (over 12%), to achieve high packing density and low free volume. The combination of components should have negative heat of mixing, inhibiting crystal nucleation and prolonging the time the molten metal stays in state.

The alloys of, , , and other glass formers with magnetic metals have high , with low  and high. Usually the conductivity of a metallic glass is of the same low order of magnitude as of a molten metal just above the melting point. The high resistance leads to low losses by s when subjected to alternating magnetic fields, a property useful for e.g. s. Their low coercivity also contributes to low loss.

Amorphous metals have higher tensile yield strengths and higher elastic strain limits than polycrystalline metal alloys, but their ductilities and fatigue strengths are lower. Amorphous alloys have a variety of potentially useful properties. In particular, they tend to be stronger than crystalline alloys of similar chemical composition, and they can sustain larger reversible ("elastic") deformations than crystalline alloys. Amorphous metals derive their strength directly from their non-crystalline structure, which does not have any of the defects (such as ) that limit the strength of crystalline alloys. One modern amorphous metal, known as, has a tensile strength that is almost twice that of high-grade. However, metallic glasses at room temperature are not and tend to fail suddenly when loaded in, which limits the material applicability in reliability-critical applications, as the impending failure is not evident. Therefore, there is considerable interest in producing s consisting of a metallic glass matrix containing dendritic particles or fibers of a ductile crystalline metal.

Perhaps the most useful property of bulk amorphous alloys is that they are true glasses, which means that they soften and flow upon heating. This allows for easy processing, such as by, in much the same way as. As a result, amorphous alloys have been commercialized for use in sports equipment, medical devices, and as cases for electronic equipment.

Thin films of amorphous metals can be deposited via technique as protective coatings.

Applications
Currently the most important application is due to the special magnetic properties of some ferromagnetic metallic glasses. The low magnetization loss is used in high efficiency transformers at line frequency and some higher frequency transformers. Amorphous steel is a very brittle material which makes it difficult to punch into motor laminations. Also (such as theft control passive ID tags,) often uses metallic glasses because of these magnetic properties.

Amorphous metals exhibit unique softening behavior above their glass transition and this softening has been increasingly explored for thermoplastic forming of metallic glasses. Such low softening temperature allows for developing simple methods for making composites of nanoparticles (e.g. ) and BMGs. It has been shown that metallic glasses can be patterned on extremely small length scales ranging from 10 nm to several millimeters. This may solve the problems of where expensive nano-molds made of silicon break easily. Nano-molds made from metallic glasses are easy to fabricate and more durable than silicon molds. The superior electronic, thermal and mechanical properties of BMGs compared to polymers make them a good option for developing nanocomposites for electronic application such as devices.

Ti40Cu36Pd14Zr10 is believed to be noncarcinogenic, is about three times stronger than titanium, and its nearly matches s. It has a high  and does not produce abrasion powder. The alloy does not undergo on solidification. A surface structure can be generated that is biologically attachable by surface modification using laser pulses, allowing better joining with bone.

Mg60Zn35Ca5, rapidly cooled to achieve amorphous structure, is being investigated, at Lehigh University, as a for implantation into s as screws, pins, or plates, to fix fractures. Unlike traditional steel or titanium, this material dissolves in organisms at a rate of roughly 1 millimeter per month and is replaced with bone tissue. This speed can be adjusted by varying the content of zinc.

Ti-based metallic glass, when made into thin pipes, have a high tensile strength of 2100 MPA, elastic elongation of 2% and high corrosion resistance. Using these properties, a Ti–Zr–Cu–Ni–Sn metallic glass was used to improve the sensitivity of a Coriolis flow meter. This flow meter is about 28-53 times more sensitive than conventional meters, which can be applied in fossil-fuel, chemical, environmental, semiconductor and medical science industry.

Zr-Al-Ni-Cu based metallic glass can be shaped into 2.2-5 mm by 4 mm pressure sensors for automobile and other industries, and these sensors are smaller, more sensitive, and possess greater pressure endurance compared to conventional stainless steel made from cold working. Additionally, this alloy was used to make the world's smallest geared motor with diameter 1.5mm and 9.9mm to be produced and sold at the time.

Modeling and theory
Bulk metallic glasses (BMGs) have now been modeled using atomic scale simulations (within the framework) in a similar manner to. This has allowed predictions to be made about their behavior, stability and many more properties. As such, new BMG systems can be tested, and tailored systems; fit for a specific purpose (e.g. replacement or  component) without as much  searching of the  and  trial and error.